Premixed Syngas Combustion: Modeling and Application to a Swirl-Stabilized Combustor
Esmail A M Mokheimer, Fahad Mohammed Majhoud Alzahrani , Mohamed Habib
كلية الهندسة-جامعة الملك فهد للبترول والمعادن · السعودية
The stringent regulations of harmful gases and pollutants, such as nitrogen oxides, lead to the use of alternative fuels in order to lower these emissions. Hydrogen is one of the cleanest fuels. When burnt with oxidizer, it produces water and no other harmful emissions. Thus, it has the potential to become a major contributor to a near-zero emission future. However, currently, technology limitations, mostly associated with storage and transportation, limit its use in a wide range. A very promising alternative is synthetic gas (syngas), which is composed mainly of hydrogen (H2) and carbon monoxide (CO). Lean premixed (LPM) combustion of syngas can be one of the most promising technologies for increased combustion efficiency and reduced emissions. In this thesis, LPM syngas combustion characteristics have been studied numerically. LPM syngas laminar flames are modeled in zero- and one-dimensional forms using a detailed chemistry model (GRI-Mech. 3.0) to understand their most important basic properties, namely adiabatic flame temperature, laminar flame speed, and NO emissions. An emphasis has been given to the importance of syngas reaction mechanisms by studying some of the available reduced chemical mechanisms and how accurate they are in predicting the basic properties of LPM syngas laminar flames studied. Finally, LPM syngas combustion in a real geometry lab-scale swirl-stabilized combustor is modeled using computational fluid dynamics (CFD) to study the effect of swirl number, syngas composition, and equivalence ratio on flame characteristics and emissions. The adiabatic flame temperature of syngas was observed to increase with equivalence ratio, operating pressure, and preheat temperature, and decrease with hydrogen volume percent in syngas. The laminar flame speed increased with increasing equivalence ratio, hydrogen content in the syngas and preheat temperature, and decreased with increasing operating pressure. The NO production was also observed to increase with increasing equivalence ratio and preheat temperature. However, it decreased with increasing hydrogen in the syngas mixture. As the operating pressure increased, NO formation decreased at low equivalence ratios, and increased at high equivalence ratio. At very lean conditions, the NO predictions by the GRI-Mech. 3.0 were highly under-predicted by the reduced mechanisms. Different combination of these factors resulted in varying degree of discrepancy by the mechanisms understudy. It can be concluded that there is a need for developing more robust chemical mechanisms that could predict LPM syngas flames properties, especially at high preheat temperatures and operating pressures. In addition, experimental data for the effect of pressure on H2/CO laminar flame speeds with air (O2+N2) as the oxidizer is required and will be helpful for validating the developed kinetic models for syngas oxidation at high pressures. For the swirl-stabilized flames, the swirl geometry was found to have a significant effect on the different flame properties. The different strength levels of gases recirculation resulted in different values of flame temperature. The flame was found to be shorter for high swirl numbers. This gave higher residence time of combustion products, which reduced CO emissions. On the other hand, the higher capability of hydrogen to ignite and burn increased the flame temperature and NOX levels locally. Increasing H2/CO ratio resulted in higher flame temperatures, shorter flame lengths, and weaker reverse flow associated with the inner recirculation zones. In addition, upstream flame propagation (flashback phenomenon) occurred beyond H2 = 50%. Higher NOX emissions and lower CO and CO2 emissions resulted from increasing H2/CO ratio. The equivalence ratio was found to have the most significant influence on flame temperature and emissions. Undesirable levels of NO were observed for equivalence ratios beyond φ=0.6, while undesirable levels of CO were recorded for equivalence ratios below φ=0.6. Moreover, increasing equivalence ratio caused CO2 emissions to increase.