رسائل دكتوراة
English
2018
Synthesis and Identification of Some Thiazole Derivatives and Study of Flammability for Some Thermosetting Polymers
شيماء عدنان بهجت, صابرين فرحان جواد كاظم, محمد ناظم بهجت
كلية التربية-جامعة القادسية · العراق
In this study, twenty one heterocyclic organic compounds, These compounds were divided into three groups A, B and C, as shown in the diagram (I,II,III) :-azocompound(A, B and C) which prepared by reacting between salicylaldehyde and (2-amino-6-bromobenzothiazole, 2-amino-6-methylbenzothiazole and2-amino-6-nitrobenzothiazole) respectively in presence of HCl and NaNO2.-Chalcones compound(A: 1-3; B: 1-3; C: 1-3) which prepared by reacting between azo compound (A, B and C) with (4-hydroxy-3-methoxyacetophenone,4-hydroxyacetophenone and 4-methoxyacetophenone ) respectively in presence of NaOH.-Schiff bases compound(A4, A5, A6, B4, B5, B6, C4, C5, C6) which prepared by reacting between azo compound (A, B and C) and (2-amino-5-methyl phenol, 2-amino-6-methyl pyridine and 4-chloroaniline) in presence of glacial acetic acid .These compounds were identified by using FT-IR,1H-NMR and 13C-NMR. and a small amount of these compounds were used to measure and studied their effectiveness in inhibition of the flame and increasing the resistance to ignition of the unsaturated polyester and epoxy resins.Three sheets in dimension (13X13X0.3cm) of unsaturated polyester and epoxy resins with the additives, were prepared with a weight percentage (0.1, 0.15, 0.2, 0.25and 0.3 %),these sheets used in this work which were cut according to the (ASTM) standard are:1. Method of measuring the limiting oxygen index (LOI) using the approved method of testing (ASTM: D-2863).2. The method of measuring the rate of burning (R.B), the extent of burning (E.B) and the time of burning (TB) through the approved method of examination (ASTM: D-635).
The results obtained from these tests of the unsaturated polyester and epoxy resins,The efficiency of group additives was in the following order:A > C > B The efficiency of group additives (group A) was in the following order:A6 > A5 > A4 > A1 > A3 > A2> A The efficiency of group additives (group B) was in the following B6 > B5 > B4 > B1 > B3> B2> Band the efficiency of group additives (group C) was in the following order:C6 > C5 > C4 > C1 > C3 > C2> C The study showed that a good flame retardant was obtained in all percentages of additives and obtained a self-extinguishing in percentage 0.1% for each additives A1, A4, A5 and A6,for unsaturated polyester resin and self-extinguishing in percentage 0.1% for the additives A6 for epoxy resin, and Non-Burning occurring in the percentage 0.15% for the additives A5 and A6,for unsaturated polyester resin and the percentage 0.2% for the additive A5 and A6for epoxy resin