تصميم واصطناع مرتبطات حلقية ومعقداتها المعدنية

الموضوعات

علوم بحتة وطبيعية

روابط وملفات

التعريف والنوع

رقم الوثيقة

fc9c090a-fb1a-4c4f-9402-e22e678146b7

رقم العقد

0

نوع الوسائط

Crawler

نوع المحتوى

الرسائل العلمية

صيغة المصدر

رسائل ماجيستير

نوع الملف

pdf text

أسماء الملفات

1961030_1.pdf

بيانات النشر

ترجمة العنوان

Designing and Synthesising Macrocyclic Ligands and Their Metal Complexes

ألقاب المؤلفين

[{"name_ar":"ثناء شريتح","title_ar":"اشراف","title_en":"Supervision"},{"name_ar":"جمعة مرزا ","title_ar":"اشراف","title_en":"Supervision"},{"name_ar":"علي حسين العاسمي","title_ar":"اعداد","title_en":"Preparation"}]

اللغة

Arabic

المصدر والدورية

اسم المصدر

تصميم واصطناع مرتبطات حلقية ومعقداتها المعدنية

المحتوى والصفحات

عدد الصفحات

0

ترجمة الملخص

In this research we have Designing and synthesizing of Ten compounds based Salicylaldehyde with halide alkyl and Diamines ,containing N,O donor atoms. Initially, three organic compounds were synthesized from Salicylaldehyde with Dihalide compounds by using substitution (SN2) Reaction, to obtain dialdehyde compounds. Two new macrocyclic Ligands from dialdehyde compounds with different amines(ethylene diamine and 1,2-phenylenediamine) through the Schiff Base,have been prepared. Then, reaction of these macrocyclic ligands with some of Copper (II) Cobalt (II) and Nickle (II) ions, new organometallic complexes were obtained:1-Three Dialdehyde compounds (EDOD, OEBOD, PMBOD)2-Two Macrocyclic Compounds (DTDACT, DDTBCD)3-Three Macrocyclic Complexes with Copper (II), Cobalt (II) and Nickle (II)4-Two Macrocyclic Complexes with Copper (II) and Cobalt (II).The optimum conditions such as Homogeneous Catalyst, pH values effects of Time, and temperature were studied, to obtain compounds as a selective product with highest yield .Identification of this compounds were determined by: FT-IR, UV. vis, 1H-NMR, 13C-NMR, Elemental Analysis and AAS (Atomic Absorption spectrometry)

إشراف وإعداد

الإشراف

ثناء شريتح, جمعة مرزا

الإعداد

علي حسين العاسمي

الاقتباسات الببليوغرافية